. 2016 Jan 26;116(4):2478–2601. doi: 10.1021/acs.chemrev.5b00484

Table 2. Angular Geometries, Intermolecular I···Y Distances (r₀, Å), and Intermolecular Stretching Force Constants (k_σ, N m^–1) As Derived Experimentally from Rotational Spectroscopy in the Gas Phase for a Series of Halogen-Bonded Complexes with ClI and CF₃–I.

2.2.1.

C_s at equilibrium, C_2v in the zero-point state.

These molecules possess low barriers to internal rotation/other motion. The point group of highest symmetry achieved during the motion is given.

Table 2. Angular Geometries, Intermolecular I···Y Distances (r0, Å), and Intermolecular Stretching Force Constants (kσ, N m–1) As Derived Experimentally from Rotational Spectroscopy in the Gas Phase for a Series of Halogen-Bonded Complexes with ClI and CF3–I.