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. 2016 Feb 5;138(7):2126–2129. doi: 10.1021/jacs.5b12989

Table 1. Boron Reagent Variation.

graphic file with name ja-2015-12989a_0010.jpg

entry boron electrophile [B] temp (°C) yield (%)a of 3aa
1 BBr3b 45 0
2 BCl3b 45 0
3 B-chlorocatecholborane 45 25
4 B-chlorocatecholborane 100 75
5 B-bromocatecholborane 100 48
a

Isolated yield.

b

1.0 M solution in DCM.