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. Author manuscript; available in PMC: 2016 Apr 29.
Published in final edited form as: J Am Chem Soc. 2015 Apr 21;137(16):5292–5295. doi: 10.1021/jacs.5b01899

Table 2. Assessment of Phosphetane-Catalyzed Allylic Reductiona.

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a

See Supporting Information for full experimental details. Isolated yields are reported unless otherwise stated. Ratios (γ:α) determined by 1H NMR integration unless otherwise stated.

b

Determined by GC analysis.

c

Reaction time 10 h due to thermal instability of substrate.

d

TBDPS = tert-butyldiphenylsilyl.

e

TBS = tert-butyldimethylsilyl.

f

d.r. and relative stereochemistry of major isomer determined after TBS deprotection.