Table 1. Deuterated carbohydrates.
Carbohydrate | M R (1H) a | M R (2H) b | % 2H c (NMR) |
Glu-OMe | 194 | 217–220 | 67 |
Gal-OMe | 194 | 217–219 | 40 |
Man-OMe | 194 | 217–219 | 51 |
Arab-OMe | 164 | 188–190 | 49 |
Trehalose | 342 | 365–369 | 62 |
aMolar mass of starting carbohydrate.
bMain peak range in ESI-MS following deuteration of carbohydrate [M + Na]+.
cAverage deuteration as evaluated by 1H NMR.