Table 3. Parameters deduced from hysteresis measurements.
Hairpin | Transition state | Transition state | Transition rate |
---|---|---|---|
x→ | x→/L | k0 | |
(nm) | (s−1) | ||
DNA10 | 4.4 ± 0.2 | 0.30 | (1.0–3.0) × 10−4 |
DNA18 | 4.7 ± 0.2 | 0.28 | (3.8–8.5) × 10−5 |
RNA10 | 3.0 ± 0.2 | 0.17 | (2.9–5.5) × 10−5 |
RNA18 | 3.1 ± 0.2 | 0.17 | (3.0–10) × 10−6 |
By definition, we have x← = L − x→ and x←/L = 1 − x→/L, k0 = k(F = 0) = ν0 exp ( − E/kBT)