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Plot of initial rate vs [LDA] for Scenario 3 (Figure 14). Curve A (black) reflects the LDA order of the uncatalyzed (dimer-dominated) metalation; Curve B reflects the fully LiCl-catalyzed metalation (high LiCl portion of Scenario 2 in Figure 14). The curves result from numerical integrations (simulations) of the model in Scheme 7.
