Table 1. Summary of the physical parameters derived from electrical, specific heat, and optical measurements for LixFe7Se8.
LixFe7Se8 | x = 0 (Fe7Se8) | x = 0.53 | x = 0.89 |
σ300K (Ω−1 cm−1) | 3,300 | 1,277 | 877 |
σ2K (Ω−1 cm−1) | 4,386 | 77 | 0.86 |
ωp (cm−1) | 11,300 | 11,000 | 10,700 |
nIR (cm−3) | 4.3 × 1021 | 4.0 × 1021 | 3.8 × 1021 |
nCp (cm−3) | 4.6 × 1021 | 2.2 × 1021 | 2.1 × 1020 |
N(EF)IR (m−3 J−1) | 1.2 × 1047 | 1.18 × 1047 | 1.16 × 1047 |
N(EF)Cp (m−3 J−1) | 1.3 × 1047 | 9.7 × 1046 | 4.5 × 1046 |
nIR(x)/nIR(Fe7Se8) | 100% | 93% | 88% |
nCp(x)/nCp(Fe7Se8) | 100% | 48% | 5% |
nc | — | 4 × 1014 | 9.5 × 1018 |
nIR/nc | — | 1 × 107 | 4 × 102 |
μ300K (cm3/V s) | 4.8 | 2 | 1.4 |
μ2K (cm3/V s) | 6.0 | 0.2 | 2.6 × 10−2 |
T0 (K) | — | ~0.2 | 5,373 |
ξ (Å) | Inf | ~360 | 12.3 |