Table 1.
Parameters | Cu(II) ions concentration | |||
---|---|---|---|---|
25 mg/dm3 | 50 mg/dm3 | 75 mg/dm3 | 100 mg/dm3 | |
PFO | ||||
q e,exp | 6.21 | 14.49 | 18.70 | 24.93 |
q 1,cal | 0.11 | 0.09 | 0.06 | 0.05 |
k 1 | 0.023 | 0.019 | 0.014 | 0.013 |
t 1/2 | 0.211 | 0.203 | 0.248 | 0.258 |
R 2 | 0.6923 | 0.9829 | 0.9429 | 0.8994 |
PSO | ||||
q 2,cal | 6.23 | 12.49 | 18.71 | 24.96 |
k 2 | 1.198 | 0.852 | 1.200 | 1.309 |
h | 46.510 | 132.999 | 420.222 | 815.470 |
t 1/2 | 0.192 | 0.068 | 0.064 | 0.052 |
R 2 | 1.0000 | 1.0000 | 1.0000 | 1.0000 |
IPD | ||||
k i1 | 0.02 | 0.02 | 0.06 | 0.006 |
k i3 | 0.008 | 0.01 | 0.007 | 0.004 |
k i3 | 0.004 | 0.004 | 0.004 | 0.004 |
R i,1 2 | 0.9791 | 0.6157 | 0.9442 | 0.9213 |
R i,3 2 | 0.9508 | 0.9782 | 0.9535 | 0.8997 |
R i,3 2 | 1.0000 | 1.0000 | 1.0000 | 1.0000 |
Elovich | ||||
A | 7.35 | 4.63 | 3.35 | 2.31 |
B | 53.82 | 37.94 | 55.20 | 71.17 |
R 2 | 0.9992 | 0. 9992 | 0.9768 | 0.8692 |