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. Author manuscript; available in PMC: 2017 Jan 18.
Published in final edited form as: Angew Chem Int Ed Engl. 2015 Dec 3;55(3):1070–1074. doi: 10.1002/anie.201507494

Table 3.

Scope of Heterocyclic Diarylmethanes in Allylic Alkylation Reactions.[a]

graphic file with name nihms765615u4.jpg
Entry Ar Ar′ Base Ratio (4:base:2a) Product Yield (%)
1 2-Py Ph NaHMDS 1:2:1.2 5aa 91
2 3-Py Ph NaHMDS 1:3:1.2 5ba 91
3 4-Py Ph LiHMDS 1:2:1.2 5ca 93
4 3-Py 3-Py LiHMDS 1:3:1.2 5da 90
5 2-thienyl Ph NaHMDS 1:2:1.2 5ea 82

6 graphic file with name nihms765615t2.jpg LiHMDS 1:3:1.2 5fa 81
[a]

Reactions conducted on a 0.1 mmol scale.