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. 2016 Jan 5;110(1):188–196. doi: 10.1016/j.bpj.2015.11.012

Table 3.

Parameters for the Equation of State, Eq. 3, Applied to Different Thermodynamic Processes

Processa TS+ (°C) ΔS+(J mol−1 K−1) TH+ (°C) ΔH+ (kJ mol−1) Reference
PC transfer 44 ± 3 64 ± 4 −18 ± 5 21 ± 2 (6)
Protein unfold 110 ± 6 18 ± 1 102 ± 5 5.7 ± 0.3 (33)b
Peptide transfer 104 ± 12 15 ± 3 72 ± 9 11.5 ± 0.8 (34)
HC transfer 106 ± 5 −6 ± 4 40 ± 6 6 ± 2 (27)c
124 ± 3 74 ± 3 93 ± 2 1.6 ± 0.7 (35)d
a

PC transfer is the transfer of diacyl phosphatidylcholine and lysophosphatidylcholine monomers to micellar aggregates. Protein-unfold is the thermal unfolding of globular proteins per residue. Peptide transfer is the dissolution of solid cyclic dipeptides, GG, AG, AA, LG, and VV, per residue in water. HC transfer is the dissolution of liquid aromatic and aliphatic hydrocarbons in water (27), or of gaseous n-alkanes (35).

b

For a limited range of proteins (33), and excluding parvalbumin (see Murphy et al. (3)).

c

Excluding propylbenzene (see Murphy et al. (3) and Baldwin (2)).

d

CnH2n+2 for n = 2−8.