Table 2.
13C NMR (100 MHz) Data (δ) of Compounds 1–5 (δC in ppm)
| position | 1a/1ba | 2a/2ba | 3a | 4a | 5 |
|---|---|---|---|---|---|
| 1 | 127.1 | 127.1 | 127.1 | 127.0 | 127.1 |
| 2 | 109.3 | 109.3 | 109.6 | 109.5 | 109.5 |
| 3 | 146.9 | 146.9 | 147.0 | 147.0 | 147.0 |
| 4 | 148.2 | 148.1 | 148.3 | 148.2 | 148.3 |
| 5 | 114.3 | 114.3 | 114.6 | 114.3 | 115.0 |
| 6 | 123.3 | 123.3 | 123.3 | 123.3 | 123.3 |
| 7 | 145.3 | 145.2 | 145.6 | 145.4 | 145.0 |
| 8 | 115.6 | 115.5 | 115.6 | 115.6 | 115.3 |
| 9 | 167.1 | 167.3 | 167.0 | 167.3 | 167.2 |
| 1′ | 130.0 | 130.3 | 131.4 | 131.2 | 130.8 |
| 2′ | 109.9 | 110.0 | 109.5 | 109.0 | 108.6 |
| 3′ | 146.9 | 146.9 | 146.9 | 146.8 | 146.8 |
| 4′ | 145.8 | 145.6 | 145.8 | 145.3 | 145.6 |
| 5′ | 114.9 | 114.9 | 114.9 | 114.9 | 114.3 |
| 6′ | 120.6 | 120.6 | 120.9 | 121.0 | 119.0 |
| 7′ | 83.5 | 82.8 | 74.6 | 72.3 | 71.9 |
| 8′ | 82.3 | 82.6 | 86.6 | 84.7 | 83.7 |
| 9′ | 63.9 | 63.8 | 63.2 | 62.8 | 62.7 |
| 1″ | 136.0 | 136.2 | 137.6 | 137.6 | 130.9 |
| 2″ | 112.6 | 112.6 | 112.5 | 112.6 | 103.9 |
| 3″ | 150.9 | 151.0 | 151.0 | 151.6 | 153.7 |
| 4″ | 146.7 | 146.8 | 146.3 | 145.3 | 134.1 |
| 5″ | 118.9 | 119.2 | 120.6 | 119.5 | 153.7 |
| 6″ | 121.0 | 121.2 | 121.2 | 121.3 | 103.9 |
| 7″ | 32.1 | 32.0 | 32.2 | 32.2 | 134.0 |
| 8″ | 30.6 | 30.6 | 30.62 | 30.6 | 123.8 |
| 9″ | 63.9 | 63.9 | 63.8 | 63.9 | 65.0 |
| 1‴ | 127.1 | 127.1 | 127.1 | 127.1 | 127.2 |
| 2‴ | 109.5 | 109.5 | 109.6 | 109.6 | 109.4 |
| 3‴ | 146.9 | 146.9 | 147.0 | 147.0 | 147.0 |
| 4‴ | 148.1 | 148.1 | 148.2 | 148.2 | 148.1 |
| 5‴ | 114.9 | 114.9 | 114.9 | 115.0 | 114.9 |
| 6‴ | 123.4 | 123.5 | 123.4 | 123.4 | 123.3 |
| 7‴ | 145.1 | 145.2 | 145.2 | 145.2 | 145.0 |
| 8‴ | 115.2 | 115.6 | 114.9 | 115.2 | 115.6 |
| 9‴ | 167.5 | 167.6 | 167.5 | 167.5 | 167.2 |
| OCH3-3 | 56.2 | 56.2 | 56.2 | 56.2 | 56.2 |
| OCH3-3′ | 56.2 | 56.1 | 56.1 | 56.2 | 56.2 |
| OCH3-3″ | 56.0 | 55.9 | 56.0 | 56.1 | 56.4 |
| OCH3-3‴ | 56.2 | 56.2 | 56.2 | 56.2 | 56.2 |
| OCH3-5″ | 56.4 | ||||
| OCH3-7′ | 57.4 | 57.4 |
1a/1b and 2a/2b showed the same 13C NMR data.