Table 1. Surface basicity and catalytic activity of different metal glycerolates towards transesterification of crude Jatropha oil with ethanol.
Entry | Metal glycerolate | Surface basic strength | Conversiona (%) |
---|---|---|---|
1 | MnGly | 6.8 < H_ < 7.2 | 95.8 |
2 | FeGly | 4.8 < H_ < 6.8 | 12.0 |
3 | CoGly | 6.8 < H_ < 7.2 | 50.5 |
4 | ZnGly | 6.8 < H_ < 7.2 | 80.0 |
aReaction conditions: reaction temperature (150 °C), feedstock-to-ethanol molar ratio (1:20), catalyst loading (6 wt.%) and reaction time (4 h).