Table 2. Catabolic reactions considered in the inorganic nitrogen oxidation–reduction microbial ecosystem.
Nitrogen oxidation and reduction | ||||
---|---|---|---|---|
Xi | Catabolism reaction | Ne,mole− moleD−1 | ΔG01a, kJ moleD−1 | ΔG01/e−, kJ mole−−1 |
1 | NH4+ + 1.5O2 → NO2− + 2H+ + H2O | 6 | −269.90 | −44.98 |
2 | NO2− + ½ O2 → NO3− | 2 | −76.50 | −38.25 |
3 | NH4+ + 2O2 → NO3− + 2H+ + H2O | 8 | −346.40 | −43.30 |
4 | C2H3O2− + 8/5NO3− + 13/5H+ → 4/5N2 + 2CO2 + 14/5H2O | 8 | −805.60 | −100.70 |
5 | C2H3O2− + 8/3 NO2− + 11/3 H+ → 4/3N2 + 2CO2 + 10/3H2O | 8 | −977.50 | −122.19 |
6 | C2H3O2− + 2NO3− + 3H+ → N2O + 2CO2 + 3H2O | 8 | −689.40 | −86.18 |
7 | C2H3O2− + 4NO2− + 5H+ → 2N2O + 2CO2 + 4H2O | 8 | −831.00 | −103.88 |
8 | C2H3O2− + 4N2O + H+ → 4N2 + 2CO2 + 2H2O | 8 | −1270.50 | −158.81 |
9 | C2H3O2− + 4NO3− + H+ → 4NO2− + 2CO2 + 2H2O | 8 | −547.70 | −68.46 |
10 | C2H3O2− + NO3− + 3H+ → NH4+ + 2CO2 + H2O | 8 | −507.30 | −63.41 |
11 | C2H3O2− + 4/3NO2− + 11/3H+ → 4/3NH4+ + 2CO2 + 2/3H2O | 8 | −493.80 | −61.73 |
12 | NH4+ + NO2− → N2 + 2H2O | 4 | −362.80 | −90.70 |
Considering pH 7 and 298.15 K. Liquid concentrations 1 m and 1 bar for gas components (N2, N2O and CO2).