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. Author manuscript; available in PMC: 2017 Apr 4.
Published in final edited form as: Angew Chem Int Ed Engl. 2016 Mar 11;55(15):4711–4715. doi: 10.1002/anie.201601056

Figure 1.

Figure 1

Evolution of a P411 catalyst for nitrene transfer to progressively larger aryl-alkyl sulfides. Experiments were performed using whole cells overexpressing the P411 variant, resuspended to OD600 = 30, with 5 mM sulfide and 5 mM tosyl azide. Results are the average of experiments performed with duplicate cell cultures, each used to perform duplicate chemical reactions. P = P411BM3-CIS T438S.