Table 2.
0.2 mmol of substrate, 0.8 mmol of ArI, 0.02 mmol of Pd(OAc)2 (10 mol%), 0.04 mmol of L10 (20 mol%), 0.6 mmol of Ag2CO3, 1 mL of t-AmylOH, 50 mL sealed tube, 90 °C (oil), 20 h. The yields are isolated yields.
1 equiv of AgO2CnBu was added and the reaction temperature was 100 °C.
The dr value of 1i is 2/1; The configuration in the table is the major isomer.