Table 2.
Summary of data for enzymatic upgrading of butyric acid and butanol to various derivatives.
| Product | Donor | Acceptor | Lipase | System | Yield (Time) | T (°C) | Reference |
|---|---|---|---|---|---|---|---|
| Butyl-acetate | Acetic acid | Butanol | Novozym 435 | Hexane | 91.5% (2.5 h) | 40 | Martins et al. (2011) |
| Butyl-acetate | Acetic acid | Butanol | Novozym 435 | Hexane | 94% (2.5 h) | 46 | Martins et al. (2013a) |
| Butyl-acetate | Acetic acid | Butanol | Lipozyme IM20 | Hexane | 90% (96 h) | 45 | Kumar and Rao (2003) |
| Butyl-butyrate | Butyric acid | Butanol | Type VII | Heptane | 75% (24 h) | 41 | Santos and de Castro (2006) |
| Butyl-butyrate | Butyric acid | Butanol | Lipozyme RM-IM | Hexane | >90% (16 h) | 40 | Lorenzoni et al. (2012) |
| 94.8% (24 h) | |||||||
| Butyl-butyrate | Butyric acid | Butanol | Lipozyme TL-IM or MCI-TLL | Hexane | ∼95% (7 ha) | 50 | Martins et al. (2013b) |
| Butyl-butyrate | Butyric acid | Butanol | Lipozyme TL-IM | Hexane | 95% (3 h) | 48 | Martins et al. (2013c) |
| Butyl-butyrate | Butyric acid | Butanol | Mucor sp. lipase | Cyclohexan | 95% (24 h) | 35 | Abbas and Comeau (2003) |
| Butyl-caproate | Caproic acid | Butanol | Mucor sp. lipase | Cyclohexan | 100% (24 h) | 35 | Abbas and Comeau (2003) |
| Ethyl-butyrate | Butyric acid | Ethanol | Lipozyme TL-IM | Solvent-free | 90% (6 h) | 30 | Paludo et al. (2015) |
| Butyl-butyrate | Butyric acid | Butanol | Novozym 435 | Hexadecane in aqueous broth media | 34 mM | 37 | van den Berg et al. (2012) |
The time was taken by a figure of the article.