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. 2016 Mar 17;363(8):fnw064. doi: 10.1093/femsle/fnw064

Table 2.

Summary of data for enzymatic upgrading of butyric acid and butanol to various derivatives.

Product Donor Acceptor Lipase System Yield (Time) T (°C) Reference
Butyl-acetate Acetic acid Butanol Novozym 435 Hexane 91.5% (2.5 h) 40 Martins et al. (2011)
Butyl-acetate Acetic acid Butanol Novozym 435 Hexane 94% (2.5 h) 46 Martins et al. (2013a)
Butyl-acetate Acetic acid Butanol Lipozyme IM20 Hexane 90% (96 h) 45 Kumar and Rao (2003)
Butyl-butyrate Butyric acid Butanol Type VII Heptane 75% (24 h) 41 Santos and de Castro (2006)
Butyl-butyrate Butyric acid Butanol Lipozyme RM-IM Hexane >90% (16 h) 40 Lorenzoni et al. (2012)
94.8% (24 h)
Butyl-butyrate Butyric acid Butanol Lipozyme TL-IM or MCI-TLL Hexane ∼95% (7 ha) 50 Martins et al. (2013b)
Butyl-butyrate Butyric acid Butanol Lipozyme TL-IM Hexane 95% (3 h) 48 Martins et al. (2013c)
Butyl-butyrate Butyric acid Butanol Mucor sp. lipase Cyclohexan 95% (24 h) 35 Abbas and Comeau (2003)
Butyl-caproate Caproic acid Butanol Mucor sp. lipase Cyclohexan 100% (24 h) 35 Abbas and Comeau (2003)
Ethyl-butyrate Butyric acid Ethanol Lipozyme TL-IM Solvent-free 90% (6 h) 30 Paludo et al. (2015)
Butyl-butyrate Butyric acid Butanol Novozym 435 Hexadecane in aqueous broth media 34 mM 37 van den Berg et al. (2012)
a

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