Table 2. The values of coupling parameters from the model Hamiltonian about layers’ coupling which are obtained by fitting the splitting values from Table 1 for 2L-ab, 3L-aba, 3L-abc, 4L-abab and 4L-abca with the different layers and stacking orders.

Stacking way	VB-Γ(eV)			CB-Λ (eV)			CB-K (10−2 eV)			VB-K(10−2 eV)
	M1	M2	M3	M1	M2	M3	M1	M2	M3	M1	M2	M3
2L-ab	0.3194	–	–	0.1529	–	–	2.71	–	–	3.05	–	–
3L-aba	0.2835	0.0850	–	0.1432	0.0440	–	1.89	1.81	–	2.34	1.75	–
3L-abc	0.2515	0.0720	–	0.1485	0.0110	–	3.19	−0.55	–	3.46	−0.40	–
4L-abab	0.2725	0.0690	0.0230	0.1442	0.0165	−0.0150	1.80	0.62	−1.70	2.20	0.69	−2.02
4L-abca	0.2770	0.0690	0.0295	0.1497	0.0095	0.0030	4.23	−0.40	0.58	4.44	−0.275	0.715

Note that M₁, M₂ and M₃ represent the nearest-neighbor, second near-neighbor and third near-neighbor layer-coupling parameters, respectively.