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. Author manuscript; available in PMC: 2016 Apr 11.
Published in final edited form as: Spectrochim Acta Part B At Spectrosc. 2016 Feb 1;116:21–27. doi: 10.1016/j.sab.2015.11.008

Table 6.

Recovery values and difference values of Zn-based commercial sunscreens tested using the correction factors from Matrix A working standards.

Sample Label claim Zn (wt%) [Zn]XRF (wt%) %RV1 [Zn]ICP-MS (wt%) %RV2 %DV
SUN01XZ   6.43 7.96 ± 0.01 124.35 7.13 ± 0.02 111.25 11.12
SUN02XZ   4.82 6.04 ± 0.01 125.75 4.70 ± 0.01 97.92 24.92
SUN03XZ   6.43 8.71 ± 0.01 136.08 7.32 ± 0.62 114.38 17.35
SUN05TZ   3.21 3.50 ± 0.00 109.33 3.11 ± 0.03 96.89 12.16
SUN06XZ 16.06 17.9 ± 0.01 110.92 17.14 ± 0.15 106.21 4.10
SUN07XZ 16.06 18.6 ± 0.01 115.49 16.54 ± 0.17 102.73 11.78
SUN09XZ 11.24 12.3 ± 0.01 109.98 11.22 ± 0.50 100.18 9.33
SUN10XZ 16.06 17.9 ± 0.01 111.65 16.78 ± 0.24 104.22 6.88
SUN11XZ 16.06 18.7 ± 0.01 116.26 17.52 ± 0.18 108.82 6.61
SUN12XZ 16.06 18.6 ± 0.01 115.64 18.16 ± 0.17 112.80 2.49
SUN14TZ   4.82 5.52 ± 0.01 115.08 5.65 ± 0.28 117.71 −2.26
SUN16XZ 14.94 14.8 ± 0.01 99.24 16.21 ± 0.20 108.72 −9.12
SUN17XZ 20.08 19.6 ± 0.01 97.26 18.85 ± 0.14 93.83 3.59
SUN18XZ   5.62 7.61 ± 0.01 135.83 6.19 ± 0.15 110.54 20.55
SUN19XZ 18.07 11.1 ± 0.01 61.56 9.19 ± 0.06 50.66 19.46
SUN20XZ   7.31 9.10 ± 0.01 124.64 7.37 ± 0.84 102.19 19.84
SUN21XZ 20.08 19.7 ± 0.01 98.12 18.59 ± 0.21 92.54 5.86
SUN22XZ   5.54 6.95 ± 0.01 126.32 5.63 ± 0.03 102.73 20.62
SUN23XZ 14.94 15.2 ± 0.01 101.81 14.95 ± 0.05 100.40 1.40
SUN24XZ   9.40 11.4 ± 0.01 120.84 9.93 ± 0.03 105.74 13.30
SUN25XZ 15.06 18.6 ± 0.01 123.02 14.91 ± 1.10 98.94 21.72
SUN26XZ 16.06 17.8 ± 0.01 110.34 16.59 ± 0.04 104.78 5.17
SUN28TZ   4.82 5.01 ± 0.01 104.37 4.93 ± 0.01 102.71 1.54
SUN30XZ   7.23 8.88 ± 0.01 123.27 7.75 ± 0.42 107.64 13.52
SUN32XZ 16.06 18.1 ± 0.01 112.15 17.32 ± 0.01 107.27 4.45
SUN35TZ   9.32 11.1 ± 0.01 118.46 11.20 ± 0.31 120.22 −1.47