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. 2015 Jun 16;54(31):9066–9069. doi: 10.1002/anie.201502924

Scheme 1.

Scheme 1

a) Traditional Pd‐catalyzed cyclization of functionalized allenes. b) Envisioned Pd‐catalyzed cyclization of enallenes with an external nucleophile. c) Observed approach of olefin‐directed Pd‐catalyzed oxidative arylation of allenes. FG=functional group. Nu=nucleophilic unit.