. Author manuscript; available in PMC: 2016 Jun 1.

Published in final edited form as: Nat Chem. 2015 Oct 5;7(12):987–994. doi: 10.1038/nchem.2366

Table 3.

Substrate scope of [Mn(^tBuPc)] -catalyzed C—H amination.

Isolated yields are average of three runs.

Conditions: 5 mol% [FePc]Cl, 5 mol% AgSbF₆, 2 equiv. Phl(OPiv)₂, 4:1 PhMe/MeCN (0.5M), rt, 8h.

^†

Used 10 mol% catalyst.

^‡

ins./azir. rati

^§

For Rh₂(esp)₂ see ref. 31. For Rh₂(OAc)₄ and [Rh₂(S-nap)₄] see ref. 1. For [Ru₂(hp)₄] see ref. 15.

^¶

10% of 1° C—H animation also isolated.