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. Author manuscript; available in PMC: 2016 Apr 20.
Published in final edited form as: Nat Commun. 2014 Dec 16;5:5440. doi: 10.1038/ncomms6440

Figure 1. X-ray crystal structures of 1 and 2.

Figure 1

a, Displacement ellipsoid plots (30% probability level) of the two crystallographically independent moieties of [FeIII(TAML)(O2)]2– in [K(2.2.2-cryptand)(CH3CN)][K(2.2.2-cryptand)]3-[FeIII(TAML)(O2)]2 (see also Supplementary Fig. 1 and Supplementary Tables 1). The O-O bond distances for the two independent moieties are 1.323(3) Å and 1.306(7) Å, respectively. Disorder of the O7-O8 and the H atoms have been omitted for the sake of clarity. b, Displacement ellipsoid plots (30% probability level) of the two crystallographically independent moieties of [MnIV(TAML)(O2)]2− in [K(2.2.2-cryptand)(CH3CN)][K(2.2.2-cryptand)]3-[MnIV(TAML)(O2)]2 (see also Supplementary Fig. 2 and Supplementary Tables 2). The O-O bond distances for the two independent moieties are 1.415(2) Å and 1.412(3) Å, respectively. Disorder of the O7-O8 and the H atoms have been omitted for the sake of clarity.