Table 1. MS and MS/MS of MMAE.
MS | MMAE | |
---|---|---|
m/z | ||
(a) | ||
[M + H]+ | 718.4 | |
[M + Na]+ | 740.4 | |
[M + K]+ | 756.4 | |
(b) | ||
Precursor ion | [M + H]+ | 321.2 |
506.3 | ||
687.4 | ||
[M + Na]+ | 496.3 | |
682.3 | ||
722.4 | ||
[M + K]+ | 512.2 | |
544.3 | ||
698.3 |
(a) The three positive-ion peaks derived from MMAE were observed by MS analysis: single-charge hydrogen and sodium and potassium adducts, denoted as [M + H]+, [M + Na]+, and [M + K]+, respectively. (b) MS/MS fragments of MMAE determined from each of the three positive-ion peaks of MMAE.