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. 2016 Apr 21;6:24954. doi: 10.1038/srep24954

Table 1. MS and MS/MS of MMAE.

MS MMAE
m/z
(a)
[M + H]+ 718.4
[M + Na]+ 740.4
[M + K]+ 756.4
(b)
Precursor ion [M + H]+ 321.2
506.3
687.4
[M + Na]+ 496.3
682.3
722.4
[M + K]+ 512.2
544.3
698.3

(a) The three positive-ion peaks derived from MMAE were observed by MS analysis: single-charge hydrogen and sodium and potassium adducts, denoted as [M + H]+, [M + Na]+, and [M + K]+, respectively. (b) MS/MS fragments of MMAE determined from each of the three positive-ion peaks of MMAE.