Table 1.
Entry | Cond. | O2b | [DBT]c | Total [CHO]c | [TDA]c | [PDA]c | [2-HDEA]c | [HDA]c |
---|---|---|---|---|---|---|---|---|
1 | DBTOd, hνe | N | 470 ± 170 | 250 ± 100 | 6.7 ± 2.3 | 220 ± 90 | 28 ± 8 | 2.8 ± 1.7 |
2 | hν | N | – | 26 ± 11 | n.d.h | 29 ± 9 | n.d. | −2 ± 7 |
3 | DBTO | N | 6.9 ± 7.7 | 1.1 ± 2.0 | n.d. | n.d | n.d | 1.1 ± 2.0 |
4 | DBTO, hν | Y | 360 ± 100 | 730 ± 240 | 13 ± 4 | 630 ± 230 | 80 ± 30 | 4.5 ± 1.7 |
5 | hν | Y | – | 71 ± 18 | 2 ± 3 | 52 ± 17 | 13 ± 7 | 3.7 ± 2.4 |
6 | DBTO | Y | −2 ± 4 | 0.0 ± 2.0 | n.d. | n.d. | n.d. | 0.0 ± 2.0 |
7 | Ozonef | – | – | 730 ± 260 | 15 ± 5 | 700 ± 190 | n.d. | 14 ± 4 |
8 | Airg | – | – | 0.6 ± 1.2 | n.d. | n.d. | n.d. | 0.6 ± 1.2 |
Samples of 653 μM of pLPC in 6 mL acetonitrile contained within fused-silica test tubes were used for all experiments.
(N) Oxygen removed from samples by sparging with argon for 30 minutes. (Y) samples irradiated without sparging.
Concentrations in μM determined by GC-MS reported as mean ± 95% confidence interval for four or more experiments. A Q-test with 99% confidence was performed to remove outlying data due to gross errors.
Samples Contains 1.0 mM of DBTO.
sample irradiated with eight broadly emitting fluorescent bulbs centered at 350 nm for five hours.
Ozone gas gently passed through sample for 10 minutes.
Air gently passed through sample for 10 minutes.
not detected.