Table 4.
position | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 |
---|---|---|---|---|---|---|---|---|
1 | 200.4, C | 196.2, C | 196.2, C | 197.7, C | 198.1, C | 155.8, C | 200.2, C | 200.0, C |
2 | 54.4, CH2 | 52.3, CH2 | 53.4, CH2 | 52.4, CH2 | 52.1, CH2 | 113.6, CH | 53.5, CH2 | 53.3, CH2 |
3 | 70.8, C | 74.9, C | 71.6, C | 69.7, C | 70.9, C | 139.0, C | 71.6, C | 69.9, C |
4 | 44.7, CH2 | 73.8, CH | 44.1, CH2 | 44.3, CH2 | 42.5, CH2 | 122.0, CH | 43.0, CH2 | 43.2, CH2 |
4a | 148.6, C | 151.6, C | 149.5, C | 146.5, C | 134.0, C | 137.8, C | 135.1, C | 135.2, C |
5 | 130.5, CH | 132.4, CH | 120.3, CH | 124.7, CH | 131.6, CH | 128.8, CH | 130.3, CH | 130.5, CH |
6 | 131.1, CH | 129.5, CH | 157.2, C | 138.7, CH | 122.1, CH | 123.6, CH | 122.3, CH | 122.6, CH |
6a | 133.7, C | 135.0, C | 124.0, C | 71.4, C | 153.0, C | 131.9, C | 148.2, C | 148.3, C |
7 | 183.2, C | 180.7, C | 180.1, C | 67.7, CH | 54.9, CH2 | 183.7, C | 99.0, CH | 99.1, CH |
7a | 120.2, C | 120.4, C | 123.1, C | 127.4, C | 129.9, C | 120.3, C | 123.3, C | 123.2, C |
8 | 159.7, C | 135.0, C | 158.7, C | 156.9, C | 158.2, C | 159.5, C | 154.0, C | 154.1, C |
9 | 112.5, CH | 118.8, CH | 118.5, CH | 111.0, CH | 115.4, CH | 112.4, CH | 112.0, CH | 112.0, CH |
10 | 135.1, CH | 136.3, CH | 135.2, CH | 128.5, CH | 128.6, CH | 134.8, CH | 131.8, CH | 131.9, CH |
11 | 122.5, CH | 118.9, CH | 117.7, CH | 119.6, CH | 122.8, CH | 122.6, CH | 112.3, CH | 111.9, CH |
11a | 146.4, C | 137.7, C | 136.9, C | 142.6, C | 139.3, C | 146.9, C | 148.7, C | 148.7, C |
12 | 64.3, CH | 184.6, C | 186.2, C | 70.1, CH | 199.8, C | 65.2, CH | 77.7, CH | 77.6, CH |
12a | 142.0, C | 134.5, C | 138.9, C | 46.6, CH | 128.1, C | 139.6, C | 126.3, C | 126.5, C |
12b | 130.1, C | 134.1, C | 127.9, C | 125.8, C | 130.6, C | 120.7, C | 127.6, C | 127.1, C |
13 | 56.3, CH3 | 56.9, CH3 | 56.9, CH3 | 55.6, CH3 | 56.5, CH3 | 56.3, CH3 | 56.0, CH3 | 56.0, CH3 |
14 | 29.6, CH3 | 26.8, CH3 | 30.6, CH3 | 28.4, CH3 | 29.6, CH3 | 22.0, CH3 | 30.1, CH3 | 29.1, CH3 |
1' | 99.4, CH | 100.9, CH | ||||||
2' | 70.4, CH | 70.4, CH | ||||||
3' | 70.4, CH | 72.0, CH | ||||||
4' | 72.1, CH | 72.5, CH | ||||||
5' | 70.7, CH | 70.4, CH | ||||||
6' | 18.4, CH3 | 18.5, CH3 |
Assignments are based on COSY, HMBC, HSQC, and NOESY experiments.