Table 2. Apparent activation energies (Ea’) for the direct decomposition of NO.
Mode/Temperature conditions | Catalyst | Ea’ (kJ/mol)a | References |
---|---|---|---|
Direct decomposition of NO | – | 364 | 40 |
CRM, 579–733 K | Cu/ZSM-5 | 123 | 41 |
CRM,500–650 °C | Cu-ZSM-5 | 71–121 | 42 |
CRM,500–650 °C | Cu-ZSM-5 | 75.6 | this work |
MCRM,200–250 °C | Cu-ZSM-5 | 25.04 | this work |
MCRM,120–200 °C | CuO-Cu-ZSM-5 | 22.47–25.73 | this work |
MCRM, 360–400 °C | CuO-Cu-ZSM-5 | 19.55–22.81 | this work |
aEa’ was calculated using the Arrhenius equation; was used to calculate the kinetic data41.