Table 1. Spin-Hamiltonian parameters used for simulation of the W-band EPR spectra of 5.
gx | gy | gz | Jx (cm−1) | Jy (cm−1) | Jz (cm−1) | ||
---|---|---|---|---|---|---|---|
{Cr7Ni-O2C-terpy} | 1.78 | 1.78 | 1.74 | J12 | −0.14 | 0.34 | 0.17 |
{Cr7Ni-O2C-py} | 1.74 | 1.78 | 1.78 | J23 | −0.07 | 0.17 | 0.34 |
Co(II) | 1.78 | 4.25 | 6.50 |
J12, J23 and g={gx,gy,gz} are diagonal tensors.