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. Author manuscript; available in PMC: 2016 Apr 28.
Published in final edited form as: J Phys Chem Lett. 2016 Feb 22;7(5):820–824. doi: 10.1021/acs.jpclett.6b00019

Figure 1.

Figure 1

Exchange-induced self-decoupling of intermolecular hydrogen-bond scalar coupling hJ. The graph shows the theoretical relationship between the residence time of a complex and the apparent hJ constants (on a logarithmic scale for each axis). The curves were obtained with Eqs. 1–6 together with R1,P = 1 s−1 and the intrinsic hJ constants indicated.