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A) Reactivity towards external substrates shown by SP [(12-TMC)2CuII2(O22−)]2+ (right) compared to generic reactivity of EP and SP/O cores. B) UV/Vis changes and kinetic analysis (inset) for the reaction of [(12-TMC)2CuII2(O22−)]2+ (λmax = 364 nm) with acid to generate 2 equivalents of [(12-TMC)CuII]2+ (λmax = 590 nm) and H2O2.
