Table A.1.
Concentration | Vari able | Reaction Rate | Value | |
---|---|---|---|---|
[HBrO2] | x (M) | k1 | 2 × 106h (M−1s−1) | |
[Br−] | y (M) | k2 | 2h2a (s−1) | |
[Ferrin] | z (M) | k3 | 3 × 103 (M−1s−1) | |
[Br2] | u (M) | k4 | 42ha (s−1) | |
Concentration | Constant | k5 | 5 × 109 h (M−1 s−1) | |
[H+] | h = 0.16 (M) | k6 | 10 (s−1) | |
|
a = 0.30 (M) | k7 | 29m (s−1) | |
[MA] | m = 0.40 (M) | k8 | 9.3m (s−1) | |
[BrMA] | b = 0.10m (M) | k9 | 0.07m − 0.12m (s−1) | |
Other Constants | k10 | 0.05m (s−1) | ||
c0 = 0.0034 (M) | kr | 2 × 108 (M−1s−1) | ||
cmin = 6.1 × 10−5 (M) | kred | 5 × 106 (M−1s−1) | ||
bC = 0.05 (M) | k(I) | 0 – 10−4 (s−1) | ||
Coefficients of Diffusive Transport | ||||
μx = 0.0020 (s−1) | μy = 0 (s−1) | μz = 0 (s−1) | μu = 0.987 (s−1) |