Table A.1.
Variables, constants, and reaction rates in the VE model and coefficients of diffusive transport used to couple oscillators. Values of the concentration constants and other constants are specific to our simulations; the reaction rates excluding k(I) are specific to the FKN mechanism. For m > 0.1, k9 = 0.12m; otherwise, k9 = 0.7m. We let k(I) = 10−4 s−1 to suppress oscillations.
Concentration | Vari able | Reaction Rate | Value | |
---|---|---|---|---|
[HBrO2] | x (M) | k1 | 2 × 106h (M−1s−1) | |
[Br−] | y (M) | k2 | 2h2a (s−1) | |
[Ferrin] | z (M) | k3 | 3 × 103 (M−1s−1) | |
[Br2] | u (M) | k4 | 42ha (s−1) | |
Concentration | Constant | k5 | 5 × 109 h (M−1 s−1) | |
[H+] | h = 0.16 (M) | k6 | 10 (s−1) | |
|
a = 0.30 (M) | k7 | 29m (s−1) | |
[MA] | m = 0.40 (M) | k8 | 9.3m (s−1) | |
[BrMA] | b = 0.10m (M) | k9 | 0.07m − 0.12m (s−1) | |
Other Constants | k10 | 0.05m (s−1) | ||
c0 = 0.0034 (M) | kr | 2 × 108 (M−1s−1) | ||
cmin = 6.1 × 10−5 (M) | kred | 5 × 106 (M−1s−1) | ||
bC = 0.05 (M) | k(I) | 0 – 10−4 (s−1) | ||
Coefficients of Diffusive Transport | ||||
μx = 0.0020 (s−1) | μy = 0 (s−1) | μz = 0 (s−1) | μu = 0.987 (s−1) |