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. Author manuscript; available in PMC: 2017 Feb 21.
Published in final edited form as: Chem Commun (Camb). 2016 Feb 21;52(15):3155–3158. doi: 10.1039/c5cc09718e

Scheme 1.

Scheme 1

Preparation of gold complexes [(IPr)Au(L)]A, L = PPh3, A = ClO4 (2a), A = CF3SO3 (2b), A = ClO4, L = PEt3 (3), L = P(OPh)3 (4), L = AsPh3 (5), L = bipy (6). (i) AgClO4 or AgOSO2CF3 (1 eq.), CH2Cl2/Diethyl ether 1:1, from 0 °C to RT, 15’. (ii) L (1 eq.), CH2Cl2/Diethyl ether 2:1, RT, 15 min.