Table 5.
Steady-state method | Steady-state equations | Parameters to be estimated |
---|---|---|
Solved for initial values | A = k0 ∕ (k2B + k7) | k1, k2, k3, k4 |
B = k1k7 ∕ (k2(k0 − k1)) | ||
(Standard) | C = k1 ∕ k3 | k0, k7 |
D = k1 ∕ k4 | ||
Equation of B solved for k7 | A = k0 ∕ (k2B + k7) | k1, k2, k3, k4 |
k7 = Bk2(k0 − k1)∕k1 | ||
C = k1 ∕ k3 | k0, B | |
D = k1 ∕ k4 | ||
Equation of B solved for k0 | A = k0 ∕ (k2B + k7) | k1, k2, k3, k4 |
k0 = k1k7 ∕ (Bk2) + k1 | ||
C = k1 ∕ k3 | B, k7 | |
D = k1 ∕ k4 | ||
Standard | k0 = k1 + Δk0 | k1, k2, k3, k4 |
A = k0 ∕ (k2B + k7) | ||
with additional | B = k1k7 ∕ (k2(k0 − k1)) | |
parameter transformation | C = k1 ∕ k3 | Δk0, k7 |
D = k1 ∕ k4 |