Table 1. Comparison of the FT catalytic performance of various cobalt-based catalysts*.
| Sample | CO conversion (%) | C5+ selectivity (%) | CoTY† |
|---|---|---|---|
| CoS | 27 | 95 | 4.0 |
| CoDTiS | 34 | 95 | 5.0 |
| CoCNTA | 28 | 92 | 4.2 |
CoTY, cobalt time yield; FT, Fischer–Tropsch.
*All data were obtained after 20 h of time on stream where stable catalytic performance at testing conditions was achieved. Reaction conditions: reaction temperature=215 oC, gas hourly space velocity (GHSV) standard temperature and pressure (STP)=3,600 ml gcat−1 h−1, H2/CO=2, pure syngas, total pressure=40 bar. The catalysts tested have already been evaluated in the FT reaction at 215 oC about 3 days.
†Cobalt time yield (10−5 molco gCo−1 s−1, molar CO conversion rate per gram of Co per hour).