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. 2016 May 16;6:26067. doi: 10.1038/srep26067

Table 2. Reaction rate constants (k) of fructose dehydration at different temperatures.

  Entry T ( °C) k(min−1) k1(min−1) k2(min−1) k3(min−1)
A: Acidic ILs 1 100 0.00399 ± 2.83 × 10−4 0.00053 ± 2.83 × 10−5 1.3E-05 ± 2.19 × 10−6 0.003275 ± 4.74 × 10−4
2 120 0.01205 ± 6.72 × 10−4 0.009665±1.34 × 10−4 0.000116 ± 7.78 × 10−6 0.00265 ± 1.56 × 10−4
3 140 0.03202 ± 0.002638 0.02178 ± 3.96 × 10−4 0.000804 ± 6.54 × 10−5 0.01121 ± 8.63 × 10−4
4 160 0.08802 ± 6.20 × 10−3 0.04375 ± 7.21 × 10−4 0.00515 ± 4.24 × 10−4 0.037116 ± 3.2 × 10−3
B: Alkaline ILs 5 120 0.000262 ± 7.42 × 10−5 0.000123 ± 4.96 × 10−6 8.89E-06 ± 1.91 × 10−7 0.000083 ± 8.49 × 10−7
6 140 0.001329 ± 1.2 × 10−5 0.000892 ± 6.15 × 10−5 2.36E-05 ± 3.04 × 10−6 0.000408 ± 1.17 × 10−4
7 160 0.008017 ± 1.46 × 10−4 0.00596 ± 1.7 × 10−4 0.000097 ± 3.25 × 10−6 0.001757 ± 1.08 × 10−4
8 180 0.03333 ± 1.32 × 10−4 0.02489 ± 4.53 × 10−4 0.000341 ± 3.82 × 10−5 0.00865 ± 5.79 × 10−4

Conditions: 0.25 g catalyst, 0.5 g fructose, 60 mL DMSO; acidic and alkaline ILs were [MIMPS]3PW12O40 and [AEMIM]BF4.