Table 2. Reaction rate constants (k) of fructose dehydration at different temperatures.
Entry | T ( °C) | k(min−1) | k1(min−1) | k2(min−1) | k3(min−1) | |
---|---|---|---|---|---|---|
A: Acidic ILs | 1 | 100 | 0.00399 ± 2.83 × 10−4 | 0.00053 ± 2.83 × 10−5 | 1.3E-05 ± 2.19 × 10−6 | 0.003275 ± 4.74 × 10−4 |
2 | 120 | 0.01205 ± 6.72 × 10−4 | 0.009665±1.34 × 10−4 | 0.000116 ± 7.78 × 10−6 | 0.00265 ± 1.56 × 10−4 | |
3 | 140 | 0.03202 ± 0.002638 | 0.02178 ± 3.96 × 10−4 | 0.000804 ± 6.54 × 10−5 | 0.01121 ± 8.63 × 10−4 | |
4 | 160 | 0.08802 ± 6.20 × 10−3 | 0.04375 ± 7.21 × 10−4 | 0.00515 ± 4.24 × 10−4 | 0.037116 ± 3.2 × 10−3 | |
B: Alkaline ILs | 5 | 120 | 0.000262 ± 7.42 × 10−5 | 0.000123 ± 4.96 × 10−6 | 8.89E-06 ± 1.91 × 10−7 | 0.000083 ± 8.49 × 10−7 |
6 | 140 | 0.001329 ± 1.2 × 10−5 | 0.000892 ± 6.15 × 10−5 | 2.36E-05 ± 3.04 × 10−6 | 0.000408 ± 1.17 × 10−4 | |
7 | 160 | 0.008017 ± 1.46 × 10−4 | 0.00596 ± 1.7 × 10−4 | 0.000097 ± 3.25 × 10−6 | 0.001757 ± 1.08 × 10−4 | |
8 | 180 | 0.03333 ± 1.32 × 10−4 | 0.02489 ± 4.53 × 10−4 | 0.000341 ± 3.82 × 10−5 | 0.00865 ± 5.79 × 10−4 |
Conditions: 0.25 g catalyst, 0.5 g fructose, 60 mL DMSO; acidic and alkaline ILs were [MIMPS]3PW12O40 and [AEMIM]BF4.