Table 5. Isomerization of Various Substituted Allyl Alcohols Using “Good” Pd Nanoparticle (5% mol Pd and 5 mmol H2 gas).
Entry | Allyl alcohol |
Time | Hydrogenation product |
Yielda | Isomerization product |
Yielda |
---|---|---|---|---|---|---|
3 | 8 h | 0% | 100% | |||
4 | 8 h | 0% | 100% | |||
5 | 8 h | 0% | 100% | |||
6 | 8 h | 0% | 57% | |||
7 | 8 h | 6% | 33% | |||
8 | 8 h | 3% | 3% |
Yields were obtained by 1H NMR.