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. Author manuscript; available in PMC: 2016 May 17.
Published in final edited form as: Langmuir. 2012 Sep 24;28(40):14502–14508. doi: 10.1021/la302653u

Table 5. Isomerization of Various Substituted Allyl Alcohols Using “Good” Pd Nanoparticle (5% mol Pd and 5 mmol H2 gas).

Entry Allyl
alcohol
Time Hydrogenation
product
Yielda Isomerization
product
Yielda
3 graphic file with name nihms-785410-t0011.jpg 8 h graphic file with name nihms-785410-t0012.jpg 0% graphic file with name nihms-785410-t0013.jpg 100%
4 graphic file with name nihms-785410-t0014.jpg 8 h graphic file with name nihms-785410-t0015.jpg 0% graphic file with name nihms-785410-t0016.jpg 100%
5 graphic file with name nihms-785410-t0017.jpg 8 h graphic file with name nihms-785410-t0018.jpg 0% graphic file with name nihms-785410-t0019.jpg 100%
6 graphic file with name nihms-785410-t0020.jpg 8 h graphic file with name nihms-785410-t0021.jpg 0% graphic file with name nihms-785410-t0022.jpg 57%
7 graphic file with name nihms-785410-t0023.jpg 8 h graphic file with name nihms-785410-t0024.jpg 6% graphic file with name nihms-785410-t0025.jpg 33%
8 graphic file with name nihms-785410-t0026.jpg 8 h graphic file with name nihms-785410-t0027.jpg 3% graphic file with name nihms-785410-t0028.jpg 3%
a

Yields were obtained by 1H NMR.