Skip to main content
. Author manuscript; available in PMC: 2017 May 4.
Published in final edited form as: J Am Chem Soc. 2016 Apr 26;138(17):5467–5478. doi: 10.1021/jacs.6b02019

Scheme 6.

Scheme 6

Total synthesis of the oxo-polyene macrolide (+)-roxaticin via enantioselective alcohol C-H allylation and crotylation.a

aFor graphical summaries of prior total syntheses, see Supporting Information.