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. Author manuscript; available in PMC: 2017 Jan 1.
Published in final edited form as: Anal Sci. 2016;32(1):35–40. doi: 10.2116/analsci.32.35

Table 1.

Benchtop system Arg Cit Tau Hist Glu Asp
Basal Physiological Range (μM)2628 .68 .42 5–20 .0047–.0067 8–22 .8–1.6
Calibration range (μM) 0.1–10 0.1–10 0.1–10 0.1–10 0.1–10 0.1–10
Regression coefficient (R2) 0.9956 0.9897 0.9940 0.9990 0.9792 0.9854
Limit of detection (S/N = 3) /μM 0.05 0.05 0.05 0.05 0.25 0.05
Limit of quantification (S/N = 10) /μM 0.15 0.15 0.15 0.15 1.0 0.15
Migration Time % RSD 1.81 1.46 1.26 1.34 1.85 2.61
Theoretical Plates /m 746485 693960 872808 473232 565178 600081
Peak Resolution 1.29 1.16 0.97 1.15 1.10 0.15
Portable system
Basal Physiological Range (μM)2628 .68 .42 5–20 .0047–.0067 8–22 .8–1.6
Calibration range (μM) 2.0–50 2.0–50 2.0–25 2.0–15 2.0–50 2.0–50
Regression coefficient (R2) 0.9956 0.9834 0.9870 0.9977 0.9931 0.9904
Limit of detection (S/N = 3) /μM 0.25 0.36 0.42 0.37 1.31 1.21
Limit of quantification (S/N = 10) /μM 0.84 1.2 1.4 1.24 4.35 4.04
Migration Time % RSD 1.71 1.8 2.52 3.22 4.75 5.23
Theoretical Plates /m 275165 270431 331367 406943 325993 277798
Peak Resolution 2.53 0.96 1.01 6.09 2.00 3.08