. Author manuscript; available in PMC: 2016 Sep 2.

Published in final edited form as: J Am Chem Soc. 2015 Aug 21;137(34):10874–10877. doi: 10.1021/jacs.5b05142

Table 1.

Reaction of 2 (Mn^V(O)) or 3 (Cr^V(O)) with H-atom donors (C-H and O-H) with a range of BDFEs

Substrate	Mn^V(O)	Cr^V(O)	BDFE^3a
HMB^a	no	No	83
2,4,6-TTBP^b	yes	no	80
DHA^c	yes	no	77
xanthene	yes	no	73
TEMPOH	yes	yes	67

HMB = hexamethylbenzene.

2,4,6-TTBP = 2,4,6-tri-tert-butylphenol.

DHA = 9,10-dihydroanthracene.