Table 2. Structural parameters determined by GISAXSa,b,c.
| Samples | Bare AuNPs | DNA-AuNPs |
|---|---|---|
| Z1 | 9.0 ± 1.1 | 6.0 ± 1.4 |
| D1 (Å) | 99 ± 2 | 76 ± 2 |
| Λ1/D1 | 0.2 | 0.2 |
| Z2 | 8 ± 3 | 4.9 ± 1.2 |
| D2/D1 | 1.8 ± 0.1 | 1.7 ± 0.1 |
| Λ2/D1 | 0.2 | 0.3 |
| Dcutoff/D1 | 2.0 ± 0.2 | 1.8 ± 0.3 |
| Λcutoff/D1 | 0.4 ± 0.1 | 0.5 ± 0.1 |
aInclusion of the parameter Z3, D3 and Λ3 can improve the profile fitting, but is not essential.
bThe data fitting is not sensitive to the parameter
. Thus the 〈n〉 is allowed to vary in the 1.5 ± 0.5 × 10−4 Å−2 range.
cThe contribution of gas-like disorder is mainly restricted to low Qxy regime. The larger the Dcutoff, the lower the Qxy regime it dictates. So only the lower limit of the Dcutoff is considered in this study.