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. Author manuscript; available in PMC: 2016 May 27.
Published in final edited form as: J Am Chem Soc. 2015 Mar 5;137(10):3600–3609. doi: 10.1021/jacs.5b00022

Scheme 4. Substrate Scope for the New Allylic Pentafluorophenyl Thionocarbonate Rearrangement.

Scheme 4

Yields (in black) represent isolated quantities of pure secondary alcohols; enantiomeric excesses (in green) determined by chiral phase-HPLC. *This RR requires mild heating (50°C)-all others proceed smoothly at RT.