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. 2016 May 4;8(5):128. doi: 10.3390/toxins8050128

Table 1.

MRM parameters and retention times for target compounds.

Compound MRM Transition Cone Voltage (V) Collision Energy (eV) Retention Times (min) Ion Abundant Ratio (% of Base Peak)
α-amanitin 919.5 > 86.0 1,2 20 68 4.72 ± 0.2 38 ± 10
919.5 > 259.1 1 42
β-amanitin 920.5 > 86.0 1,2 20 71 4.96 ± 0.2 47 ± 9
920.5 > 259.1 1 42
γ-amanitin 903.0 > 86.0 1,2 20 70 5.45 ± 0.2 43 ± 8
903.0 > 243.1 1 41
PHD 789.4 > 157.0 1,2 20 61 7.31 ± 0.2 91 ± 4
789.4 > 86.0 1 70
PCD 847.0 > 157.0 1,2 20 64 7.87 ± 0.2 83 ± 5
847.0 > 86.0 1 70

1 the confirmation ion transitions; 2 the quantification ion transitions.