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. 2016 Jan 24;54(4):625–632. doi: 10.1093/chromsci/bmv239

Table IV.

Intraday and Interday Precision of 11 Compounds

Compound Nominal concentration (μg) Intraday (n = 6)
Interday (n = 3)
Found (μg) RSD (%) Accuracy (%) Found (μg) RSD (%) Accuracy (%)
Geniposidic acid 0.100 0.098 1.0 98.0 0.098 1.1 98.0
4.00 4.1 0.79 102.5 4.12 0.60 103.0
8.00 7.94 0.31 99.2 7.98 0.40 99.8
Chlorogenic acid 0.200 0.203 0.80 101.5 0.203 1.1 101.5
2.00 2.052 0.32 102.6 2.058 0.86 102.9
3.50 3.476 0.07 99.3 3.481 0.11 99.4
Caffeic acid 0.005 0.00495 1.3 99.0 0.00506 1.3 101.2
0.200 0.195 0.66 97.5 0.199 0.34 99.5
0.360 0.362 0.58 100.6 0.362 0.19 100.6
Geniposide 0.010 0.0102 0.94 102 0.0104 0.95 104.0
0.800 0.785 0.53 98.1 0.788 0.55 98.5
1.20 1.208 0.14 100.7 1.21 0.16 100.8
Luteoloside 0.008 0.00794 1.1 99.2 0.00805 1.2 100.6
0.300 0.306 0.86 102 0.31 0.63 103.3
0.500 0.498 0.75 99.6 0.505 0.21 101.0
Isochlorogenic acid C 0.250 0.254 0.87 101.6 0.258 1.2 103.2
1.00 1.012 0.76 101.2 1.02 0.60 102.0
1.80 1.781 0.32 98.9 1.79 0.29 99.4
Baicalin 0.200 0.195 1.40 97.5 0.199 1.1 99.5
10.0 9.87 0.90 98.7 10.05 0.36 100.5
20.0 20.13 0.18 100.7 20.18 0.32 100.9
Luteolin 0.020 0.0205 1.04 102.5 0.0204 1.2 102.0
0.500 0.497 0.84 99.4 0.498 1.0 99.6
0.900 0.876 0.48 97.3 0.906 0.42 100.7
Wogonoside 0.100 0.102 0.85 102.0 0.102 1.2 102.0
0.400 0.397 0.29 99.2 0.396 0.49 99.0
0.600 0.593 0.05 98.8 0.598 0.06 99.7
Baicalein 0.010 0.0102 1.2 102.0 0.0102 0.61 102.0
0.400 0.387 0.74 96.8 0.387 0.54 96.8
0.800 0.792 0.26 99.0 0.792 0.24 99.0
Wogonin 0.004 0.00397 1.1 99.2 0.00397 0.80 99.2
0.100 0.103 0.44 103.0 0.103 0.45 103.0
0.200 0.207 0.26 103.5 0.207 0.30 103.5