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. 2015 Aug 12;137(35):11432–11444. doi: 10.1021/jacs.5b06648

Scheme 3. Major Iron Species Formed in Situ and Their Reaction Pathways for the FeCl2(SciOPP) (1-Cl2) Catalyzed Kumada and Suzuki–Miyaura Cross-Couplings of Phenyl Nucleophiles and Secondary Alkyl Halides.

Scheme 3

Estimated rates are given for the transformations at 25 °C.