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. 2015 Aug 12;137(35):11432–11444. doi: 10.1021/jacs.5b06648

Table 1. Suzuki–Miyaura Cross-Couplings with FeCl2(SciOPP) (1-Cl2) and Fe(η6-Biphenyl)(SciOPP) (2) Precatalysts.

2.2.

catalyst R time (h) Chp-Ph yield (%) ChpCl (unreacted) (%)
1-Cl2 n-butyl 4 93a 0
  t-butyl 4 89 2
2 t-butyl 4 63 32
  t-butyl 6 83 17
a

The results with R = n-butyl are from ref (42).