Table 2. Mössbauer Parameters of Mesitylated Iron(II)–Bisphosphine Complexes50,51.
complex | geometry | sample | δ (mm/s) | ΔEQ (mm/s) |
---|---|---|---|---|
FeMes2(SciOPP) | sq. planar | solid | 0.29 | 3.58 |
froz. soln. | 0.28 | 3.67 | ||
FeMes2(PEt2Ph)2 | sq. planar | solid | 0.31 | 4.63 |
FeMes2(dppe) | sq. planar | solid | 0.33 | 4.53 |
FeMes2(depe) | dist. tetra. | solid | 0.39 | 1.71 |
FeMesBr(SciOPP) | dist. tetra | solid | 0.52 | 1.97 |
froz. soln. | 0.52 | 2.12 |