. 2015 Aug 12;137(35):11432–11444. doi: 10.1021/jacs.5b06648

Table 4. GC Analysis of the Products Formed upon Reaction of in Situ Generated Mono- and Bis-Phenylated Iron(II)–SciOPP with Bromocycloheptane at 25 °C^a.

PhMgBr (equiv)	time (s)	Chp-Ph (%)	cycloheptene (%)
1	5	84	22
1	30	84	22
1	90	84	22
2	5	87	93
2	30	88	95
2	90	89	96

Yields are with respect to iron. A minor amount of biphenyl is also observed (∼3% and 10% for the 1 equiv and 2 equiv PhMgBr reactions, respectively).

Table 4. GC Analysis of the Products Formed upon Reaction of in Situ Generated Mono- and Bis-Phenylated Iron(II)–SciOPP with Bromocycloheptane at 25 °Ca.

Table 4. GC Analysis of the Products Formed upon Reaction of in Situ Generated Mono- and Bis-Phenylated Iron(II)–SciOPP with Bromocycloheptane at 25 °C^a.