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. Author manuscript; available in PMC: 2016 Jun 1.
Published in final edited form as: Acc Chem Res. 2015 Sep 3;48(10):2744–2753. doi: 10.1021/acs.accounts.5b00260

Figure 9.

Figure 9

The N-heterocycle influences the peroxo O–O bond length in all of the peroxo compounds examined in this series, including 4, even though they are well outside the typical bonding range.