Table 1.
Substrate | Hyperfine Coupling Constants, G | Assignment | ||
---|---|---|---|---|
aN | aH | aN | ||
2′-deoxyadenosine | 15.42 | 19.95 | 2.58 | N-centered, exocyclic NH2 |
| ||||
2′-deoxycytidine | 15.38 | 18.95 | 2.02 | N-centered |
| ||||
Thymidine | 15.88 | 19.5 | 2.71 | N-centered |
| ||||
2′-deoxyguanosine | 15.6 | 20.27 | 2.56 | N-centered, N3 position |
ESR-Spin trapping studies were carried out as described in the Methods Section.