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. Author manuscript; available in PMC: 2016 Jun 2.
Published in final edited form as: ACS Catal. 2016 Jan 25;6(3):1451–1454. doi: 10.1021/acscatal.5b02558

Chart 2.

Chart 2

Arene scope of chemoenzymatic arylationa

aHal: as in Chart 1 with the halide source and RebH variant/loading indicated. Pd: as in Chart 1 using 1.5 equiv. 4-MeO-C6H4-B(OH)2. b0.05 equiv. Pd(OAc)2 & SPhos, 1.5 equiv. 4-MeO-C6H4-B(OH)2, 2 equiv. K3PO4, 20% v/v H2O/dioxane, 100 °C, 12h.