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. Author manuscript; available in PMC: 2016 Oct 28.

Published in final edited form as: Chem Commun (Camb). 2015 Oct 28;51(84):15402–15405. doi: 10.1039/c5cc05993c

Fig. 3 — The molecular structure of Tp^tBu,MeCr(η²-C₂(SiMe₃)₂) (6, 30% probability level). Selected interatomic distances (Å) and angles (°): Cr–C25, 2.0480(19);Cr–C26, 2.0835(18); C25–C26, 1.288(3); Cr–N1, 2.1015(15); Cr–N3, 2.1614(16); Cr–N5, 2. 1504(16); N_Tp–Cr–N_Tp,avg, 87.7; N1–Cr–C25/C26_centroid, 172.5; α (angle of deviation of alkyne centroid from B–Cr axis) = 49.3°.