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(a) Plot of the observed pseudo-first-order rate constant (kobs) vs concentrations of HOTf for the oxidation of HMB (2.0 × 10−2 M) by MnV(O)(TBP8Cz) (1.0 × 10−5 M) in the presence of HOTf (2.0 × 10−5 – 1.0 × 10−4 M) in PhCN at 298 K. (b) Plot of the observed pseudo-first-order rate constant (kobs) vs concentrations of HMB for the oxidation of HMB (0 – 1.0 × 10−2 M) by MnV(O)(TBP8Cz) in the presence of HOTf (3.0 × 10−5 M) in PhCN at 298 K.
